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You can use the Audio Buffer Size app to find the native settings for your device... But it's probably not worth the effort of re-sampling your library unless you have specific files that won't play, in which case be sure to use a decent re-sampler like sox or at least a good frontend for it e.g. foobar2000 with the appropriate plugin.
I'm not sure if you can change anything in the system without getting deep into the rom itself, that said I read that Android L supports 96khz... whether that's implemented or not for the Moto X it doesn't look like it.
I used [link] to run a test and it shows me at 48khz.
Sounds like they may not support 48. Drop down to 41 and retest. If they all of a sudden start to work, your gun should be smoking. If they're android, try this [link] it helps to see if the device natively supports 41 or 48.