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Hey! The entire series is half off on amazon for the blu ray discs, at least it was yesterday! Let me see if I can find you a link
Found it: https://www.amazon.com/Chuck-Seasons-1-5-Complete/dp/B009GYS73S/ref=sr_1_1?ie=UTF8&qid=1478074582&sr=8-1&keywords=Chuck
Also: Shout out to /r/chuck
You're going to have to pay for all online legal streaming options.
However, you can buy the whole series from amazon for ~$50! https://www.amazon.com/Chuck-Seasons-1-5-Complete/dp/B009GYS73S/ref=sr_1_1?ie=UTF8&qid=1481222251&sr=8-1&keywords=chuck
Don't know if you are a fan of digital, but it looks like iTunes has the complete series for $60.
Amazon has the complete series on Blu-ray for $50.
I don't know why DVD is the most expensive option. That always seems silly to me.
I don't know what I'm going to do. I've only watched the series once before and just started season 4 on my second run through. I probably won't watch the whole series again for a couple of years. It may be cheaper by then.
I bought the Blurays via Amazon here: https://www.amazon.com/gp/product/B009GYS73S/ref=ppx_yo_dt_b_asin_title_o00_s00?ie=UTF8&psc=1
as the blurays are all regions. Amazon does sell the dvd's but they are region 1 only. Shipping may be cheaper if you have Prime. I have previously bought the DVD's at JB's but they aren't available on their website so you need to find them instore. Some stores have some of the seasons, others have none. I wish Amazon Prime Video would have the show just like the US, but at least they still have Psych.
Chuck: Seasons 1 to 5 the Complete Series https://www.amazon.com/dp/B009GYS73S/ref=cm_sw_r_cp_apa_gtJCzbG18AXRG