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The Prime Video release was 3.0+1.01, as clearly shown on its Amazon listing.
Note that 3.0+1.01 was also what was shown in Japanese theaters during the second half of its theatrical run.
Amazon's page for the film is already up btw (if you wanna add it to your watchlist or see the exact languages it's being subbed and dubbed into): https://www.amazon.com/dp/B098VW137N
It's pretty safe to assume that it'll be based off of the 3.0 + 1.01 version, which was what screened in Japanese theaters during the second half of its Japanese theatrical run (i.e. from June 2021 onwards) and also globally on Amazon Prime Video.
Wait, isn’t it comes out on 13th?? On its prime page the date is August 13
That's because the 4 movies haven't been enlisted onto prime yet https://www.google.com/url?sa=t&source=web&rct=j&url=https://www.amazon.com/EVANGELION-1-01-THRICE-UPON-TIME/dp/B098VW137N&ved=2ahUKEwju-cyKvqbyAhWQyzgGHdsID40QFnoECAgQAQ&usg=AOvVaw0p4koVg12iHNYLy__jPxKB there is this alt site to, until official release I think.